Sort by case weight not by H2O volume weight. H2O sorting will get old really fast
(even if you use a good tool for the job like a 21st Century Primer Pocket Plug).... This is my recommendation even if you are an OCD type reloader for F class shooting such as I am.
Why?.... the results are not repeatable.
Take any given 308 Winchester case for example, you could get +/- 0.5 grain re-measuring that case a second time.
This happens due to the Meniscus water line of the sample.... it could be convex the first time you weight it.. could be concave the second time you weigh it.
https://en.wikipedia.org/wiki/Meniscus_(liquid)
Through personal experience, I found H2O sorting to be a time consuming rabbit hole... least I did it during the winter months.
I agree 100% with Ganderite...
Some cases have more metal
AND IF the exterior dimensions of the cases are all identical (same primer pocket depth, all resized the same, same length, etc etc)...
THEN logically more weight means less internal volume.
When to sort you asked?
Sort after you fire form.... then stainless steel tumble all the carbon out, resize consistently, turn the necks, trim to identical lengths, uniform the primer pockets, debur the flash holes... Do all that machining. Rinse the cases off to get rid of any brass shavings.
After all that, you should theoretically have cases that have near identical exterior dimensions... therefore variations in case weight are inversely related to variations in case capacity.
H2O capacity sorting is a Fool's Errand (
take it from this fool who once sorted 600 cases one winter)... just weight sort empty cases after going through process I prescribed above.