I would push a 243 Win brass up over a 25 caliber expander ball - so like found in a 25-06 or 257 Roberts die, with expander ball turned down lower than normal. I do not think there will be much drama to open a neck from .24x to .25x ... The elliptical shaped expander ball in Hornady Custom dies for 9.3x57 take an 8x57JS in one step - that is, from .32x to .36x. However, if that round does chamber and is fired, pretty much need a way to bring that neck down enough to hold next bullet - and sooner or later will need something to "bump" the shoulder - like a 25 Souper FL sizing die.
I am not sure that 25 Souper / 25-08 was ever "standardized" by SAAMI - so chambers / dies might have different dimensions - I would think to use whatever 25 Souper die that I had and size down 308 Win - incrementally - trying the fit into the rifle's chamber - maybe resulting in a "false shoulder" to allow the case to be fire-formed to that chamber. If that cartridge was not standardized by SAAMI, or if that rifle was built before such standardization - then have to think like a "wildcatter" would think, and use some of those techniques to re-size and to re-load ...